Electrolyte lattice Gibbs energy

AH , AS at, AG°at Lattice enthalpy, entropy, and Gibbs energy of the crystalline electrolyte AH v, AS V, AG°V Enthalpy, entropy, and Gibbs energy of solvation of the electrolyte AG° Gibbs energy of solution of the crystalline electrolyte. Taken from Table 1 in Ref. [3], Chapter 1. 

As described in Section 2.1, the solubility of a crystalline electrolyte is detennined by the difference between the lattice Gibbs energy and the solvation energy of the electrolyte. For a given electrolyte, the solubility increases with the increase in the... 

Under electrochemical conditions and T, P = constant, adsorption isotherms can be derived using standard statistical considerations to calculate the Gibbs energy of the adsorbate in the interphase and the equilibrium condition for the electrochemical potentials of the adsorbed species i in the electrolyte and in the adsorbed state (eq. (8.15) in Section 8.2). A model for the statistical considerations consists of a 2D lattice of arbitrary geometry with Ns adsorption sites per unit area. In the case of a 1/1 adsorption, each adsorbed particle can occupy only one adsorption site so that the maximal number of adsorbed particles per unit area in the compact monolayer is determined by A ax = Ng. Then, this model corresponds to the simple Ising model. The number of adsorbed particles, A ads< and the number of unoccupied adsorption sites, No, per unit area are given by... 

---