Eigenberger model, oscillatory reactions

Effective medium theory, 37 154 Eggshell catalysts, 39 231 EH method, 37 153 EHT, see Extended Hiickel treatment Eigenberger model, oscillatory reactions, 39 80-81, 83... 

Oscillatory surface reaction models were first proposed in the second half of the 1970s and developed in two parallel strains. The buffer-step models originated with the work of Eigenberger (274) and models with coverage-dependent activation energies were first proposed by Belyaev et al. (154). 

Eigenberger (274) was the first to introduce a kinetic scheme that contained a buffer step and to discuss the stability and oscillatory behavior of this type of reaction mechanism. His model for the reaction 2A + B 2P(CO + 502 002) can be expressed as... 

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