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Eigen-Wilkins-Werner mechanism

A reaction sequence somewhat in parallel with the Eigen-Wilkins-Werner mechanism can also be expressed for the inner-sphere surface complexation of bivalent metal cations by an ionised surface hydroxyl group (cf equation (9.9a) ... [Pg.256]

A reaction rate law for the Eigen-Wilkins-Werner mechanism is developed in Section 1.5 (Eqs. 1.50, 1.52, 1.54a, 1.54c). If inner-sphere complex formation is rate limiting and the concentration of water remains constant, the rate of inner-sphere complex formation is (cf. Eq. 1,57)... [Pg.45]

See other pages where Eigen-Wilkins-Werner mechanism is mentioned: [Pg.255]    [Pg.45]    [Pg.255]    [Pg.45]   
See also in sourсe #XX -- [ Pg.256 ]



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