Eigen reaction probabilities

Figure 2. Dotted lines are the eigen-reaction-probabilities p (E) for the collinear H + H2 reaction. The solid line is their sum, the cumulative reaction probability N(E).

The value obtained for AI was 2.3RT ApK, where ApK corresponds to reaction rates that are equal to half the respective diffusion rates. The values of AI, obtained from Eigen s data[16] for a number of normal" (i.e., 0-H and N-H) acids and bases, are given in Table 10. These lead to values of E equal to 15.6-21.0 kcal (more probable values lie between 17 and 19 kcal). ... 

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