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Eclipsed vs. Staggered. Trigonal Carbons

Molecules prefer conformations that stagger bonds on neighboring tetrahedral carbons (see Chapter 5, Problem 1). Does the same apply to trigonal carbons  [Pg.75]

Organic chemists usually think of a double bond as the combination of a a bond and a 7i bond. An alternative is to consider a double bond as made up of two equivalent bent bonds (these bonds point above and below the intemuclear axis). [Pg.75]

Apply the bent-bond model to the preferred conformations of acetaldehyde and propene. Do bent-bonds maintain or remove eclipsing interactions in the equilibrium structures of the two molecules Formulate a simple rule based on the bent-bond model for predicting conformational preferences in systems containing trigonal atoms. [Pg.75]


See other pages where Eclipsed vs. Staggered. Trigonal Carbons is mentioned: [Pg.73]    [Pg.75]    [Pg.207]    [Pg.208]    [Pg.73]    [Pg.75]    [Pg.207]    [Pg.208]   


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Carbon trigonal

Eclipsed

Eclipsed/staggered

Eclipsing

Staggered

Staggerer

Staggering

Staggers

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