Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Dynamic fluxionality

Structural dynamical fluxionality Interconversion between different structural isomers at finite temperature. [Pg.15]

Ru(P-P)2 H3 ]+> P-P = diphosphine ligand Cp2Ru2(/i-H)4. Anal. 2nd derivatives [Ru(H- H)Cp(H2PCH2PH2)]+. Nuclear dynamics Fluxional TpRu(PPh3) H2SiR3 complexes. [Pg.263]

At higher temperatures, allyl complexes are no longer rigid they become dynamic, fluxional compounds. Therefore, AM2X2 spectra become AX4 spectra. Temperatures of such transitions for various compounds range from 200 to 450 K. The hafnium allyl compound [Hf( / -C3H5)4] exhibits an AX4-type spectrum even at 199 K. For dynamic... [Pg.432]

See other pages where Dynamic fluxionality is mentioned: [Pg.61]    [Pg.61]    [Pg.63]    [Pg.65]    [Pg.61]    [Pg.61]    [Pg.63]    [Pg.65]    [Pg.65]    [Pg.572]    [Pg.99]    [Pg.99]    [Pg.129]    [Pg.37]    [Pg.154]    [Pg.155]    [Pg.11]    [Pg.344]    [Pg.61]    [Pg.61]    [Pg.63]    [Pg.65]    [Pg.61]    [Pg.61]    [Pg.65]   
See also in sourсe #XX -- [ Pg.289 ]



SEARCH



Fluxionality

Fluxions

© 2024 chempedia.info