Dithiolates, lithium complexes

Benzo-l,2-dithiole-3-thiQne (77b) reacts with lithium in THF to produce a complex which is useful in the preparation of lithium hydrides (78BEP867155). Various 3-(4-dimethyl-aminophenyl-l,2-dithiolylium salts (175) and other dithiolylium salts function as dyes for polyacrylonitrile and have been proposed as sensitizers for organic photoconductors (64USP3158621, 66USP3299055, 71USP3530145, 71USP3575968). 

The methyl[ C]labelled dithiolate complex 4 has been synthesized fJ5.Ty yield) from methyl[ C]dibromobismuth(III) and lithium thiomethanolate (equation 3). 

Iododibenzobismole 331 lododiphenylbismuthine 199, 204 Lithium hexaphenylbismuthate 304 Mesitylene-bismuth chloride cr-complex 207 4-Methoxyphenylbis(4-methylphenyl)bismuthine 29 Methyl bis(4-methyl-l-naphthyl)bismuthinate 319 Methylbis(4-methylphenyl)bismuthine 34 Methylbismuth bis(O-alkyldithiocarbonate) 123 Methylbismuth dithiolates 122 Methylbis(2,4,6-triisopropylphenyl)bismuthine 24 (4-Methylphenyl)triphenylbismuthonium tetrafluoroborate 288 1-Methyltetrahydrobismole 335 Oxybis(triphenylbismuth) bis(benzenesulfonate) 281 Oxybis(triphenylbismuth) dicyanate 280 Oxybis(triphenylbismuth) diperchlorate 279... 

Lithium 2-methylmercaptobenzo-l-thiolate and dilithium benzene-1,2-dithiolate react with [CpFe(CO)2Cl] to give [CpFe(CO)2(SCeH4SMe)] and [ CpFe(CO)2)2-(S2C6H4)], respectively, The novel seleninato-complex [CpFe(C0)2 Se(0)2-Me ] may be prepared from the reactions of either [CpFe(CO)aMe] with SeOg or [CpFe(CO)2Cl] with NaiOaSeMe]. ... 

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