Dithiocarbamate complexes group

The results of these two major studies are in agreement on a relative basis. Thus the dependence of the oxidation or reduction potentials on the R2 groups was found roughly the same for all dithiocarbamate complexes. 

Zinc complexes are important as additives for rubber polymers. Dithiocarbamate complexes are most commonly used here, but bis(8-hydroxyquinolinato)zinc inhibits the thermal decomposition of poly[(trifluoroethoxy)(octafluoropentoxy)phosphazene]. The zinc is thought to complex residual P—OH groups in the polymer chain, which would otherwise lead to rearrangement and chain scission.126... 

Heard, Peter J., Main Group Dithiocarbamate Complexes. 53 1... 

The following structural types are characteristic for the group of dithiocarbamate complexes 325 and 326 for mononuclear, 327 for binculear [1, vol.2] ... 

Structures have also been determined for a variety of dithiocarbamate complexes, the dithiocar-bamate groups usually coordinating as bidentate chelates containing markedly different Sb—S bond... 

P. J. Heard, Main Group Dithiocarbamate Complexes, in Progress in Inorganic Chemistry, 53, pp. 1-70, John Wiley Sons, Inc., New Jersey (2005). 

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