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Distorted trigonal prismatic geometry

The W(OPh)(S2C2Me2)21 complex reacts with PhYH (Y = S or Se) (see Fig. 12) to form [W( YPh)2(S2C2Me2)2J. These compounds possess a distorted trigonal-prismatic geometry with the YPh ligands occupying mutually cis... [Pg.557]

In the EuZir structure (Piguet et al., 1996), five of the Zn-N bonds (2.01-2.19 A) are close to the standard 2.11 A value (Orpen et al., 1989) while the fifth one is much longer, 2.52 A. The transition metal ion may thus be considered as being five-coordinate, with distorted trigonal prismatic geometry. Its ionic radius is then 0.62 A, as compared to the... [Pg.492]

See other pages where Distorted trigonal prismatic geometry is mentioned: [Pg.78]    [Pg.196]    [Pg.240]    [Pg.29]    [Pg.1141]    [Pg.273]    [Pg.338]    [Pg.75]    [Pg.151]    [Pg.536]    [Pg.1266]    [Pg.2759]    [Pg.4962]    [Pg.4984]    [Pg.403]    [Pg.23]    [Pg.421]    [Pg.139]    [Pg.123]    [Pg.239]    [Pg.244]    [Pg.535]    [Pg.1265]    [Pg.2758]    [Pg.4961]    [Pg.4983]    [Pg.2980]    [Pg.172]    [Pg.261]    [Pg.176]   
See also in sourсe #XX -- [ Pg.240 ]



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Distorted Geometries

Prismatic

Trigonal geometry

Trigonal-prismatic

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