Discotics external fields

In summary, the turnstile represents a new example of rotation in a molecular system. The fact that phenylacetylene macrocycles form discotic liquid crystals suggests the possibility that turnstiles might function as discotic ferroelectric liquid crystals [34]. A dipole appropriately incorporated on the spindle might allow for its own rotation to be controlled rapidly and reversibly by an external field. 

The subject of liquid crystals has now grown to become an exciting interdisciplinary field of research with important practical applications. This book presents a systematic and self-contained treatment of the physics of the different types of thermotropic liquid crystals - the three classical types, nematic, cholesteric and smectic, composed of rod-shaped molecules, and the newly discovered discotic type composed of disc-shaped molecules. The coverage includes a description of the structures of these four main types and their polymorphic modifications, their thermodynamical, optical and mechanical properties and their behaviour under external fields. The basic principles underlying the major applications of liquid crystals in display technology (for example, the twisted and supertwisted nematic devices, the surface stabilized ferroelectric device, etc.) and in thermography are also discussed. 

When a discotic liquid crystal is sandwiched between two substrates (or exposed to air), the direction of the uniaxial axis can be controlled by alignment layers, external electric fields, and chiral dopants [46,47]. It is therefore possible to develop discotic compensation films with spatially varied uniaxial axis orientations. For example, Fuji Photo Film Co. developed discotic compensation films for TN LCDs. In both the TN display and discotic compensation film, the liquid crystal directors vary in the vertical direction. Each layer of nematic liquid crystal with a certain director orientation is compensated by a layer of discotic liquid crystal with the same director orientation. 

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