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Dipyridyl with bridged complexes

Deprotonation of a binuclear complex with (bpy)2ClRu moieties and 1,5-dipyridyl-l,3-pentadiene as bridging ligand yielded the cyanine-bridged complex, contrarily to the unsuccessful case of the bis(pentaammine)ruthenium complex (cf. (NH3)5Ru(py-) above) [14a], However, cyclic voltammetry and spectroelectro-chemical studies revealed that oxidation occurred at the cyanine bridging segment rather than on ruthenium atoms, thus precluding the preparation of a mixed-valence species. [Pg.3203]

See other pages where Dipyridyl with bridged complexes is mentioned: [Pg.756]    [Pg.1171]    [Pg.55]    [Pg.67]    [Pg.34]    [Pg.47]    [Pg.269]    [Pg.354]    [Pg.57]    [Pg.269]    [Pg.3201]    [Pg.48]    [Pg.255]    [Pg.178]    [Pg.59]    [Pg.55]    [Pg.563]    [Pg.745]    [Pg.748]    [Pg.754]    [Pg.755]    [Pg.88]    [Pg.11]    [Pg.970]    [Pg.664]   


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2 : 2 -Dipyridyl

Dipyridyls

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