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Diplodiatoxin

Compound 117 is also a key intermediate in the synthesis of diplodiatoxin, a toxin produced by Diplodia maydis on maize and responsible for cattle disease [99]. The two chiral centers present in 117 are transferred in the target compound and induce all other chiralities of this bicyclic strucmre constructed via an intramolecular Diels-Alder reaction (Scheme 11.29). [Pg.521]

Ichibara, A, Kawagishi, H, Tokugawa, N, Sakamura, S, Stereoselective total synthesis and stereochemistry of diplodiatoxin, a mycotoxin from Diplodia maydis. Tetrahedron Lett, 27, 1347-1350, 1986. [Pg.576]

The bicyclic system of the mycotoxin diplodiatoxin (9) was established by intramolecular Diels-Alder reaction, with the... [Pg.259]

See other pages where Diplodiatoxin is mentioned: [Pg.522]    [Pg.140]    [Pg.140]    [Pg.141]    [Pg.278]    [Pg.508]    [Pg.140]    [Pg.140]    [Pg.141]    [Pg.189]    [Pg.289]   
See also in sourсe #XX -- [ Pg.141 ]

See also in sourсe #XX -- [ Pg.141 ]



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Intramolecular Diels-Alder reaction diplodiatoxin

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