Diperiodatocuprate , oxidation with

The kinetics of the oxidation of isopropylamine by diperiodatocuprate(III) complex ion have been studied and the results are consistent with a mechanism in which dissociation of one of the periodate ligands is followed by an adduct formation between [Cu(HIOg)] and isopropylamine. Polymerization of acrylamide indicated the participation of free radicals The kinetics of the oxidation of several diols by diperiodatocuprate(III) (DPC) in aqueous alkaline media have been studied. ... 

The oxidation of isonicotinate ion by diperiodatocuprate(in) in aqueous alkali is proposed to involve the formation of an intermediate complex in a pre-equilibrium. The intermediate subsequently disproportionates in the rate-determining step.27 The oxidation of glutamic acid by dihydroxydiperiodatoargentate(III) (DPA) in alkaline medium was found to be first order with respect to DPA and glutamic acid. No free radical was detected. A mechanism has been discussed.28... 

The diperiodatocuprate(lll) (DPC) oxidation of pentoxifylline (PTX) (14) catalysed by Ru(III) in alkaline medium proceeds via a Ru(lll)-PTX complex, which reacts with DPC and decomposes to a free radical in the rate-determining step followed by a fast step to give the products. ... 

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