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Dioxygenyl cation

The product contains the 02+ (dioxygenyl) cation, which is close enough to the size of K+ that 02PtF6 and KPtFs are isomorphous. Other compounds are known that contain the 02+ ion, including 02AsF5 and 02BF4, which can be prepared by the reaction... [Pg.443]

Oxygen has an oxidation number of +2 in some fluorides [25,] which also stabilize the dioxygenyl cation 02" " [26], redox states which are not stable, of course, in solutions. The common redox reactions... [Pg.124]

The 02PtF6 contains the 02+ cation and is isomorphous with KPtF6. The 02+ cation is called the dioxygenyl cation, and it can also be prepared by the reaction... [Pg.339]

The dioxygenyl cation, 02+, exists in various media, but it has not been reported in aqueous solution. The gas-phase species is assigned AfG° = 1164.315 kJ/mol in the JANAF tables. As a very rough approximation it may be assumed that 02+ has the same free energy of... [Pg.77]

See other pages where Dioxygenyl cation is mentioned: [Pg.4]    [Pg.80]    [Pg.83]    [Pg.83]    [Pg.933]    [Pg.259]    [Pg.463]    [Pg.259]    [Pg.1415]    [Pg.1415]    [Pg.414]    [Pg.2772]    [Pg.441]    [Pg.351]   
See also in sourсe #XX -- [ Pg.80 ]

See also in sourсe #XX -- [ Pg.77 ]

See also in sourсe #XX -- [ Pg.463 ]

See also in sourсe #XX -- [ Pg.414 ]



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