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Dioxygen insertion, into

A detailed kinetic study of dioxygen insertion into 27 organocobaloximes derived from dimethyl-, dicyclohexyl- and diphenylglyoxime has been performed under thermal and photochemical conditions . The rate of O2 insertion on the nature of the equatorial glyoxime, the axial ligand, the organic group and the solvent. [Pg.291]

These complexes are easily reoxidized by dioxygen to TppFe R.i Alkyliron(III) porphyrins will undergo CO and CO2 insertion into the Fe-C bond, forming acyliron(III) (PFeC(O)R) and alkyl carboxylate (PFeOC(O)R) complexes, respectively. ... [Pg.2180]

Hydroperoxo complexes can also be obtained by a one-electron reduction of the superoxo intermediates [Ru(NH3)6]2 + is one of the most convenient reducing agents for this chemistry.15 An interesting way of preparing hydroperoxides via dioxygen activation utilizes a formal 02 insertion into M-H bond in metal hydrides examples are known for platinum, rhodium, and cobalt complexes, to name just a few.14,15... [Pg.169]

See other pages where Dioxygen insertion, into is mentioned: [Pg.126]    [Pg.501]    [Pg.67]    [Pg.103]    [Pg.284]    [Pg.209]    [Pg.277]    [Pg.992]    [Pg.170]    [Pg.126]    [Pg.501]    [Pg.67]    [Pg.103]    [Pg.284]    [Pg.209]    [Pg.277]    [Pg.992]    [Pg.170]    [Pg.20]    [Pg.143]    [Pg.306]    [Pg.231]    [Pg.22]    [Pg.361]    [Pg.87]    [Pg.101]    [Pg.155]    [Pg.302]    [Pg.48]    [Pg.282]    [Pg.325]    [Pg.29]    [Pg.264]    [Pg.299]    [Pg.409]    [Pg.2149]    [Pg.2186]    [Pg.2237]    [Pg.48]    [Pg.645]    [Pg.177]    [Pg.49]    [Pg.680]    [Pg.1236]    [Pg.91]    [Pg.172]    [Pg.183]    [Pg.185]    [Pg.202]    [Pg.14]    [Pg.67]    [Pg.219]    [Pg.2148]    [Pg.2236]    [Pg.264]   
See also in sourсe #XX -- [ Pg.198 ]



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Dioxygen insertion into element hydride bonds

Insertion into

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