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Diorganocopper conjugate addition

How might conjugate addition reactions of lithium diorganocopper reagents be used to synthesize the following compounds ... [Pg.729]

Conjugate addition of a lithium diorganocopper to an [Pg.869]

Unsaturated aldehydes and ketones often react with nucleophiles to give the product of conjugate addition, or 1,4 addition. Particularly useful is the reaction with a diorganocopper reagent, which results in the addition of an alkyl, aryl, or alkenyl group. [Pg.797]

Propose two syntheses of 4-octanone, each involving conjugate addition of a lithium diorganocopper reagent. [Pg.831]

Conjugate Addition of Lithium Diorganocopper Reagents (Section 19.8E) In... [Pg.844]

The lithium diorganocopper reaction has no direct counterpart in biological chemistry, although weTl see in Section 17.12 that conjugate addition of various other carbon-based nucleophiles to o , S-unsaturated carbonyl compounds does occur frequently in many biological pathways. [Pg.592]

The mechanism of the reaction is thought to involve conjugate nucleophilic addition of the diorganocopper anion, R2C1F, to the enone to give a... [Pg.728]

See other pages where Diorganocopper conjugate addition is mentioned: [Pg.728]    [Pg.728]    [Pg.736]    [Pg.738]    [Pg.728]    [Pg.736]    [Pg.788]    [Pg.789]    [Pg.797]    [Pg.808]    [Pg.817]    [Pg.728]    [Pg.728]    [Pg.736]    [Pg.738]    [Pg.788]    [Pg.789]    [Pg.823]    [Pg.830]    [Pg.831]    [Pg.844]    [Pg.591]    [Pg.591]    [Pg.596]    [Pg.754]    [Pg.754]    [Pg.762]    [Pg.764]    [Pg.864]    [Pg.789]    [Pg.809]    [Pg.789]   
See also in sourсe #XX -- [ Pg.755 ]



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Conjugate addition reactions of lithium diorganocopper reagents

Diorganocopper conjugate

Lithium diorganocopper reagents conjugate addition

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