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Dinuclear complexes, hydrogen bonding

Fig. 11. Intermolecular hydrogen-bonded pairs of aqua hydroxo complexes have been found in several crystal structures and are probably always present in those salts of the type cis-[ML4(H20)(0H)lX2, which yield dinuclear dihydroxo-bridged complexes upon heating in the solid state. Fig. 11. Intermolecular hydrogen-bonded pairs of aqua hydroxo complexes have been found in several crystal structures and are probably always present in those salts of the type cis-[ML4(H20)(0H)lX2, which yield dinuclear dihydroxo-bridged complexes upon heating in the solid state.
Acid Strength of Water Ligands in Dinuclear Complexes with Negligible Intramolecular Hydrogen Bond Interaction at 25°C and / = 1.0 M... [Pg.111]

Dinuclear complexes of the type [RuH(X)L2]2 (X = C1, Br L = PPh3, AsPh3) are reported to hydrogenate the C=C bond of acrylamide.18 The stoichiometric reaction of (3) with an alkene leads to the ortho-metallated complex (5).19... [Pg.233]

Coming back to the strength of hydrogen bonding in the more complicated dinuclear complexes, we note that our dinuclear Sellmann-type metal diazene complexes were chosen closely following the lines... [Pg.70]

While the hydrogen bonds could stabilize dinuclear Fe(II) complexes by more than 20%, this effect is strongly reduced in Ru(II) compounds, where the binding energy of diazene to Ru(II) itself is comparatively large. [Pg.74]

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See also in sourсe #XX -- [ Pg.70 , Pg.71 , Pg.72 , Pg.73 ]



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Complexation, hydrogen bonding

Complexes dinuclear

Dinuclear

Hydrogen complexes

Hydrogen-bonded complexes

Hydrogen-bonding complexes

Hydrogenation complexes

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