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Dinitrogen-derived ligands

Mixed Dinitrogen-Phosphine Ligand Complexes 43.3.2.1 Mononuclear derivatives... [Pg.129]

Arene complexes have also proved useful in the study of nitrogen fixation. For example, in compound CXLV the hydrogen ligands may be reversibly displaced by molecular nitrogen giving the dinitrogen derivatives (CXLVI) (Green and Silverthorn, 1973). [Pg.114]

Working with diazo compounds, known since the early 1900s to undergo loss of dinitrogen when treated with copper or copper salts, Yates described in 1952 the possibility that transition metals could form an intermediate that combined units of the diazo compound and the metal (Eq. 1, L = ligand) and acted like a carbene in addition and insertion reactions. Somewhat later, but independently, E. O. Fischer isolated and characterized stable metal carbenes that could also undergo cyclopro-panation reactions." They were derived from transition metals on the left side of the... [Pg.562]

See other pages where Dinitrogen-derived ligands is mentioned: [Pg.109]    [Pg.114]    [Pg.178]    [Pg.26]    [Pg.60]    [Pg.109]    [Pg.114]    [Pg.178]    [Pg.26]    [Pg.60]    [Pg.10]    [Pg.11]    [Pg.52]    [Pg.474]    [Pg.167]    [Pg.247]    [Pg.481]    [Pg.19]    [Pg.369]    [Pg.386]    [Pg.396]    [Pg.681]    [Pg.3]    [Pg.354]    [Pg.355]    [Pg.357]    [Pg.359]    [Pg.150]    [Pg.329]    [Pg.394]    [Pg.310]    [Pg.64]    [Pg.336]    [Pg.209]    [Pg.250]    [Pg.47]    [Pg.99]    [Pg.309]    [Pg.129]    [Pg.144]    [Pg.2]    [Pg.19]    [Pg.2763]    [Pg.2939]    [Pg.2940]    [Pg.3373]    [Pg.4019]    [Pg.4123]    [Pg.4124]   
See also in sourсe #XX -- [ Pg.114 , Pg.178 ]



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Dinitrogen

Ligand derivatives

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