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Dinitrogen bound, reactivity

Titanium cyclopentadienyl derivatives form an extensive series of dinitrogen complexes. However, when the titanium-containing precursors are bound to polymers there is no reactivity with dinitrogen comparable to that observed for the analogous derivatives in solution, and fixation is, at best, marginal (202, 220). [Pg.200]

The formation of metal-bound diazene from dinitrogen and its subsequent disproportionation is a plausible mechanism of action of nitro-genase (54). The disproportionation of free diazene is well established (Section V,A) although such reactions of metal-bound diazene are as yet unknown. The enzymatic release of a reactive species such as cis-, trans-, or iso-diazene would be unexpected but cannot be ruled out. [Pg.256]

MacLachlan EA, Fryznk MD. Synthesis and reactivity of side-on-bound dinitrogen metal complexes. Organometallics. 2006 25 1530-1543. [Pg.360]

See other pages where Dinitrogen bound, reactivity is mentioned: [Pg.290]    [Pg.362]    [Pg.290]    [Pg.1790]    [Pg.254]    [Pg.194]    [Pg.274]    [Pg.264]    [Pg.1873]    [Pg.1790]    [Pg.379]    [Pg.98]    [Pg.297]    [Pg.731]    [Pg.228]    [Pg.1790]    [Pg.173]    [Pg.190]    [Pg.195]    [Pg.281]    [Pg.274]    [Pg.589]    [Pg.145]    [Pg.274]    [Pg.264]    [Pg.61]    [Pg.272]    [Pg.304]    [Pg.374]   
See also in sourсe #XX -- [ Pg.341 ]



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Dinitrogen

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