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Dinitrobenzenesulfonyl Chloride

Reagent 1 can also be converted to an ethylene transfer reagent by condensation with benzonitrile, followed by reduction of the ketosulfoximine and dehydration (eq 6). The resulting S-vinyl-AAtosylsulfoximine reacts with stabilized anions to give cyclopropanes.The W tosyl group in A tosylsulfoximines can be cleaved reductively using sodium anthracenide.  [Pg.240]

Related Reagents. TV, 5-Dimethyl-5-phenylsulfoximine DimethylsulfoniumMethylide DimethylsulfoxoniumMethylide Diphenylsulfonium Methylide Isopropyldiphenylsulfonium Tetrafluoroborate. [Pg.240]

Carl R. Johnson Wayne State University, Detroit, MI, USA [Pg.240]

Claire Dufour Viresh H. Rawal Ohio State University, Columbus, OH, USA [Pg.240]

Alternate Names 2,4-dinitrophenylsulfonyl chloride, dNBS. Physical Data mp 102 °C fp 206.6 46.7 °C. [Pg.240]


Dinitrobenzenesulfonyl chloride [1656-44-6] M 266.6, m 102 . Crystd from benzene or benzene/pet ether. [Pg.220]

Anderson [25] determined the distribution of olefinic bonds in elastomers after derivitization with 2,4-dinitrobenzenesulfonyl chloride using a gel permeation chromatograph equipped with a photometer operating at 254 nm. It is also possible to determine olefinic linkages with a preliminary epoxidation, followed by a method to analyze for the epoxy [26],... [Pg.165]

Dinitrobenzenediazonium 2-oxide, 2080 2,4-Dinitrobenzenesulfonyl chloride, 2093 Dinitrogen oxide, 4739... [Pg.2549]

Related Reagents. ferf-Butylsulflnyl Chloride Di-teri-butyl Disulfide Benzenesulfonyl Chloride Methanesulfonyl Chloride 2-Nitrobenzenesulfonyl Chloride 4-Nitrobenzenesulfonyl Chloride 2,4-Dinitrobenzenesulfonyl Chloride. ... [Pg.108]

Synthesis of 2,4-Dinitrobenzenesulfonylhydrazine. Addition of 2,4-dinitrobenzenesulfonyl chloride to a cold, stirred solution of 95% hydrazine in THF, provides 2,4-dinitrobenzene-sulfonylhydrazine (19) in 70% yield (eq 9). ... [Pg.242]

Preparative Method by treatment of 2,4-dinitrobenzenesulfonyl chloride with 95% hydrazine in THE and crystallized from EtOH/THE ... [Pg.243]


See other pages where Dinitrobenzenesulfonyl Chloride is mentioned: [Pg.610]    [Pg.680]    [Pg.268]    [Pg.249]    [Pg.330]    [Pg.335]    [Pg.766]    [Pg.2085]    [Pg.2462]    [Pg.2544]    [Pg.680]    [Pg.220]    [Pg.156]    [Pg.680]    [Pg.2000]    [Pg.2372]    [Pg.2458]    [Pg.861]    [Pg.824]    [Pg.240]    [Pg.240]    [Pg.241]    [Pg.653]   
See also in sourсe #XX -- [ Pg.153 ]

See also in sourсe #XX -- [ Pg.85 ]

See also in sourсe #XX -- [ Pg.156 ]

See also in sourсe #XX -- [ Pg.240 , Pg.242 ]




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2.4- Dinitrobenzenesulfonamides 2,4-dinitrobenzenesulfonyl chloride

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