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Dimolybdenum complexes, oxidative

Furthermore, chemical oxidation of [Mo(CO)6] with organic molecules containing acidic hydrogen gives rise to molybdenum species in the +2, -i-3 and +A oxidation states. Higher oxidation states (r-5 and -i-6) have been observed when halogens directly oxidize [Mo(CO)6], A Mo tetranuclear complex has been obtained when hydrochloric acid reacts with the tri-p-hydroxy-dimolybdenum complex, as shown in Equation 9.2 ... [Pg.351]

Molybdenum(III) complexes include the molybdenum trihaUdes. Molybdenum trichoride [13478-18-7], trifluoride [20193-58-2], tribromide [13446-57-6], and ttiiodide [14055-75-5] are all known. The oxide dimolybdenum trioxide [1313-29-7], M02O2, and the seldom-studied sulfide analogue [12033-33-9], M02S2, are formally trivalent. [Pg.472]

For edge-sharing bioctahedral, face-sharing bioctahedral, and ethane-like molecules, ditung-sten(m chemistry parallels the dimolybdenum 111 chemistry outlined previously. One of the drawbacks to low-oxidation-state dinuclear tungsten complexes is their susceptibility to oxidation.140 415"420 However, W2(/i-Cl)2Cl4(P(CH3)2(C6H5))4 (2.6950(9) A),421 W 2(jjr... [Pg.621]

See other pages where Dimolybdenum complexes, oxidative is mentioned: [Pg.259]    [Pg.139]    [Pg.140]    [Pg.603]    [Pg.612]    [Pg.624]    [Pg.132]    [Pg.175]    [Pg.185]    [Pg.188]    [Pg.189]    [Pg.101]    [Pg.259]    [Pg.260]    [Pg.1347]    [Pg.350]    [Pg.127]    [Pg.14]    [Pg.16]    [Pg.270]    [Pg.609]    [Pg.251]    [Pg.3186]    [Pg.189]    [Pg.190]    [Pg.299]   


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Dimolybdenum

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