Dimethyl sulfide, molecular model

Make a molecular model of dimethyl sulfide How does its bond angle at sulfur compare with the C—O—C bond angle in dimethyl ether"d... 

The reaction of [tris(3-p-tolylpyrazolyl)hydroborate)]MgMe with H2S produces the monomeric hydrosulfido complex [tris(3-p-tolylpyrazolyl)hydroborate)]MgSH, which has been structurally authenticated the Mg—S bond length is 2.35 A.Other monodentate sulfur ligands include 2-(l-methylethyl)-l,3-dimethyl-l,3,2-diazaphosphorinane 2-sulfide, whose lithium complex has been modeled with molecular orbital calculations, l,3-dimethyl-2-benzylide- 2-thioxo-1,3,2-diazaphosphorinane-S,S), and A-diisopropoxythiophosporylthiobenzamine. ... 

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