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Dimethoxynaphthalene chromophore

Intramolecular hole transfer has also been investigated [34, 35], a spectacular example being that observed using the 10-bond dyad 11(10) [35]. In this system, the naphthalene (Np) and dimethoxynaphthalene (DMN) chromophores are rigidly separated, approximately 12 A apart. Pulse radiolysis of a cyclohexane solution of 11(10) at room temperature generated a statistical mixture of the two radical cations, +Np-B-DMN and Np-B-DMN+. Exergonic hole transfer from the Np radical cation to DMN in this mixture was found to occur on a subnanosecond time scale, thereby confirming that TB-mediated HT is extremely rapid, even over 10 bonds ... [Pg.1854]


See other pages where Dimethoxynaphthalene chromophore is mentioned: [Pg.66]    [Pg.27]    [Pg.66]    [Pg.162]    [Pg.66]    [Pg.27]    [Pg.66]    [Pg.162]    [Pg.230]    [Pg.283]    [Pg.198]    [Pg.461]    [Pg.207]    [Pg.32]    [Pg.835]   
See also in sourсe #XX -- [ Pg.29 , Pg.30 , Pg.31 , Pg.32 , Pg.33 , Pg.34 , Pg.35 , Pg.36 , Pg.37 , Pg.38 , Pg.58 , Pg.60 , Pg.61 , Pg.62 , Pg.69 , Pg.70 , Pg.71 , Pg.72 , Pg.73 , Pg.74 ]




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1.4- Dimethoxynaphthalene

Dimethoxynaphthalenes

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