Dihydrogen niobium complexes

However, it is important to note that the energy values, calculated for gas-phase dihydrogen-bonded complexes are usually overestimated with respect to the experimental measurements carried out in solutions. The latter is connected directly with solvent effects. In fact, the computer simulation of solvent polarity demonstrates significant lowering of the energy of formation for example, from 6.7 to 5.2 and 2.4 kcahmol, computed for niobium trihydride system 1 on going from the gas phase to n-heptane and CH2CI2. 

Lewis base complexes, 83 Dichromates, 941, 943 Dihydrogen oxidative addition niobium(II) complexes, 678 niobium(III) complexes, 660 tantalum(II) complexes, 678 tantalum(III) complexes, 660... 

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