Difluoroamino compounds

However, when the addition is performed 111 a nucleopliilic solvent such as methanol, cleavage of the imine linkage occurs to give difliioroamino compounds [78] (equation 12) W, At-Difluorotrifluoromethylamine can be prepared from or from thiocyanates, as shown in equation 13 [79, 80] Another way to produce difluoroamino compounds is the addition of fluorine to nitriles by means of AgFj [Sf ] or C0F3 [S/]... 

Uses. Its primary use is in the prepn of organic difluoroamino compounds, A 1 1 adduct of difluoramine with methyl ether can be used as a rocket proplnt, Isp 229sec at lOOOpsia. In... 

Poly (Difluoroamino)-Substituted Cyanuric and Isocyanuric Acid Derivatives. For Cyanuric Acid and Derivatives see Vol 3, C589-R ff. For Difluoroamino Compounds see Vol 5, DI258-L... 

Perfluoro-iV-cyanodiaminomethane [16408-94-9] F2NCF2N(F)C=N See Fluorine Sodium dicyanamide See Other CYANO COMPOUNDS, DIFLUOROAMINO COMPOUNDS c2f5n3... 

See other catalytic impurity incidents, difluoroamino compounds, /v-nitro... 

Samples of this and related poly-difluoroamino compounds exploded during analytical combustion. 

Many compounds containing one or more N—X bonds show unstable or explosive properties (and are also oxidants), and this topic has been reviewed [1]. Difluoroamino compounds, ranging from difluoramine and tettafluorohydrazine to polydifluoroamino compounds, are notably explosive and suitable precautions have been detailed [2,3], Preparative scale A-chlorination of ly and 2y amines by passing them over N-chlorosuccinimide is described. In presence of alumina, ly amines give the N,N -dichloro derivatives. The products must be handled with... 

N -CHLORONITROAMINES DIFLUOROAMINO COMPOUNDS HALOGEN AZIDES N -HALOIMIDES... 

CYCLIC PEROXIDES, DIACYL PEROXIDES DIALKYL PEROXIDES, Z, /-DI(BENZOYLPEROXY)ARYLIODINES DIFLUOROAMINO COMPOUNDS, DIFLUOROAMINOPOLYNITROAROMATIC COMPOUNDS... 

This group of compounds, (which combines the structural features of both the separately treated A+haloimides and difluoroamino compounds, each of high reactivity) is explosively unstable. 

See Acetonitrile A-Fluoro compounds See other DIFLUOROAMINO COMPOUNDS... 

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