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Diffuse vibrational structures bending

The Franck-Condon analysis of the Bg state shows that progressions of both the totally symmetrical V3 C-C stretch and the asymmetric HCH bending vibrations can contribute to the observed progression of 1170 cm (cf. the discussion of the UV bands below). This accounts for the first, structured, PE band whose maximum is at about 12.0 eV. The two other maxima at 12.7 and 13.4 eV then belong to the two Ag states whose interaction is likely to be one of the causes of the irregular, diffuse character of these bands. [Pg.293]

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See also in sourсe #XX -- [ Pg.193 , Pg.194 , Pg.195 , Pg.196 , Pg.197 , Pg.198 , Pg.199 ]



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