Spectroscopy diferric iron center

Structure of the Iron Center Formation of the Iron Center and Tyrosyl Radical Spectroscopy of the Diferric Iron Center Spectroscopy of the Tyrosyl Radical Redox Properties of the Iron Center Mixed-Valent Form of the Iron Center Diferrous Form of the Iron Center Inhibitors to Iron-Containing Ribonucleotide Reductase Methane Monooxygenase A. Spectroscopy of the MMOH Cluster X-Ray Structure of MMOH... 

Mossbauer, MCD, and EPR spectroscopy have been used to study the diferrous form of the iron center. EPR spectra of the fully reduced... 

It was shown by the magnetic susceptibility measurement and Mossbauer, ESR, and UN-visible spectroscopy that TBA-I shows an antiferromagnetic coupling of the two high-spin Fe centers. For example, the 8, AEq, and J values of TBA-I, diferric complexes, oxidized methane monooxygenase (abbreviated as MMOox), and oxidized ribonucleotide reductase (abbreviated as RRox) are shown in Table 1. The 5 and AEq values for TBA-I are close to those for MMOox, 1, 2, and 4 with the symmetrical iron centers, and different from those for RRox (5 = 0.53 mms, AEqi = 1.65 mms, and 82 =... 

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