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1,1-Dicarboxylic esters, acylation alkylation

A variety of external plasticizers have also been suggested for cyanoacrylates. Among these are alkyl esters of aliphatic monocarboxylic acids such as cyanoacetates aliphatic dicarboxylic esters, such as malonates, adipates, and sebacates triaromatic phosphates such as tricresyl phosphate acyl triesters of glycerine dialkyl alkylphosphonates and alkyl phthalates. Joyner and Coover state that limiting the plasticizer concentration to less than 5% will not retard the cure speed, from 5 to 20% will retard the cure rate, and over 20% plasticizer concentration seriously slows the cure rate of the adhesive. [Pg.274]

Claisen ester condensation, 6, 279 Thiazolecarboxylic acid chlorides reactions, 6, 279-280 Thiazolecarboxylic acid hydrazides synthesis, 6, 280 Thiazolecarboxylic acids acidity, 6, 279 decarboxylation, 6, 279 reactions, S, 92 6, 274 Thiazole-2-carboxylic acids decarboxylation, S, 92 Thiazole-4-carboxylic acids stability, S, 92 Thiazole-5-carboxylic acids decarboxylation, S, 92 Thiazole-4,5-dicarboxylic acid, 2-amino-diethyl ester reduction, 6, 279 Thiazole-4,5-dicarboxylic acids diethyl ester saponification, 6, 279 Thiazolediones diazo coupling, 5, 59 Thiazoles, 6, 235-331 ab initio calculations, 6, 236 acidity, S, 49 acylation, 6, 256 alkylation, S, 58, 73 6, 253, 256 analytical uses, 6, 328 antifogging agents... [Pg.873]

EtAlCb catalyzes the Friedel-Crafts acylation of alkenes with acid chlorides, the formal [3 + 2] cycloaddition of alkenes with cyclopropane-1,1-dicarboxylates (eq 21), the Friedel-Crafts alkylation of anilines and indoles with ct-aminoacrylate esters, and the formation of allyl sulfoxides from sulfinyl chlorides and alkenes. EtAlCU induces the Beckmann rearrangement of oxime sulfonates. The cationic intermediates can be trapped with enol silyl ethers (eq 22). EtAlC is the preferred catalyst for addition of the cation derived from an a-chloro sulfide to an alkene to give a cation which undergoes a Friedel-Crafts alkylation (eq 23). ... [Pg.180]


See other pages where 1,1-Dicarboxylic esters, acylation alkylation is mentioned: [Pg.304]    [Pg.365]    [Pg.843]    [Pg.843]    [Pg.83]    [Pg.90]    [Pg.262]    [Pg.22]   
See also in sourсe #XX -- [ Pg.426 , Pg.489 ]




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1,1-Dicarboxylic esters, acylation

Acyl esters

Acyls alkylation

Alkyl esters

Dicarboxylate esters

Dicarboxylic esters

Esters acylation

Esters alkylation

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