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Dicarbonyl methyl iron

Several cyclopentadienyl(alkyl)metal carbonyl derivatives have reacted with acetylenes. In some examples, insertion reactions may also be involved, although the mechanisms have not been investigated. Cyclopentadienyl(methyl)iron dicarbonyl with diphenylacetylene gave a 10% yield of cyclopen tadienyltetra-phenylcyclopentadienyliron 71). [Pg.198]

Dicarbonyl(cyclopentadienyl)[(dimethylsulfoniuni)methyl]iron(II) tetrafluoroborate... [Pg.98]

Dicarbonyl(cyclopentadienyl)[(dimethylsulfonium)methyl]iron(ll) tetrafluoroborate, Cp(CO)2FeCH2S(CH3)2BF4 (1). [Pg.98]

Dicarbonyl(cyclopentadienyl)[(di-methylsulfonium)methyl]iron(II) te-trafluoroborate, 98 Diiodomethane-Triisobutylaluminum, 114... [Pg.363]

Dicarbonyl(cyclopentadienyl)-[(dimethylsulfonium)methyl]-iron(II) tetrafluoroborate, 98 Diiodomethane-Diethylzinc, 276 Diiodomethane-Triisobutylalu-minum, 114... [Pg.379]

Bromopentacarbonylmanganese, 49 tom -Bromotetracarbonyl(methyl-methylidyne)chromium, 50 frmethylidyne)tungsten, 49 Carbonylhydridotris(triphenylphosphine)-rhodium(I), 329 Chromium carbonyl, 51 Decacarbonyldimanganese, 49 Dicarbonylcyclopentadienylcobalt, 96 Dicarbonyl(cyclopentadienyl)[(dimethyl-sulfonium)methyl]iron(II) tetrafluoroborate, 98... [Pg.405]

Dicarhonyl( cyclopentadienyl )[cyclopropyl( methoxy)methyl iron Dicarbonyl(cyclopentadienyl)(cyclo-... [Pg.1888]

Dicarbonyl(cyclopeiitadienyl)[(diinethylsulfoniuin)methyl]iron tetrafluoroborate. 13, 98 15, 117... [Pg.126]

PBF4O2WC2sH20> Tungsten, dicarbonyl(if -cyclopentadienyl) [tetrafluoroborato-(1 -)] (triphenylphosphine)-, 26 98 PBrF4N3RuCi4H2i, Ruthenium(II), tris-(acetonitrile)bromo(ft -1, S-cyclooctadiene)-, hexafluoro-phosphate(l —), 26 72 PC3H9, Phosphine, methyl-, iron complex, 28 177... [Pg.440]

Dicarbonyl(cyclopentadienyl)[(dimethyl-sulfonium) methyl] iron Tetrafluoroborate ... [Pg.198]

C2 8H3 sBFeN02P2 f Dicarbonyl(methyl)bis(trimethyIphosphine)(triphenyl-boratonitrilomethyl)iron(II), 46B, 1271 C28H36C03O8P, Octacarbonyl(tricyclohexyIphosphine)methylmethinyltri-cobalt, 43B, 1003... [Pg.403]

Dicarbonyl(if -cyclopentadienyl)[(dimethylsulfonio)methyl]iron tetrqfluoroborat ... [Pg.591]

Dicarbonyl(cyclopentadienyl)(trans-3-methyl-2-vinylcyclohexanone)iron tetrafluoroborate, 66, 97... [Pg.241]

OSg, cyc/o-Octasulfur monoxide, 21 172 O2BC2H, Boronic acid, ethyl-, 24 83 02BF4FeCiiHig, Iron(l-t-), dicarbonyl(t) -cyclopentadienyl)(-n -2-methyl-l-pro-penyl)-, tetrafluoroborate(l -), 24 166 O2BNC4H12, Borane, carboxy-compd. with trimethylamine (1 1), 25 81... [Pg.281]

DICARBONYLCu -CYCLOPENTADIENYL) (2-methyl-i-propenyl-kC )iron and DICARBONYL(n -CYCLOPENTADIENYL)(ii. 2-METHYL. l-PROPENE)IRON(l+) TETRAFLUOROBORATE... [Pg.319]

The preparation of dicarbonyl(T -cyclopentadienyl)(2-methyl-l-propenyl-KC )iron requires 3-chloro-2-methyl-l-propene (methailyl chloride), not the reagent given in Reference 1, p. 165. ... [Pg.319]

In iron reactions where the reagent was equivalent to C, described in Section 8.9.A, the iron moiety was used as an auxiliary. Iron can also stabilize cations, which then react with nucleophiles to generate new carbon-carbon bonds. 08 xhese cations are formed as iron-alkene complexes, usually by reaction of cyclo-pentadienyl dicarbonyl ferrate anion (478) with an allylic halide such as 3-chloro-2-methyl-l-propene. The... [Pg.1131]

See other pages where Dicarbonyl methyl iron is mentioned: [Pg.2014]    [Pg.465]    [Pg.1852]    [Pg.2013]    [Pg.465]    [Pg.400]    [Pg.581]    [Pg.664]    [Pg.918]    [Pg.706]    [Pg.645]    [Pg.262]    [Pg.101]    [Pg.645]    [Pg.244]    [Pg.1888]    [Pg.981]    [Pg.981]   


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Dicarbonyl methyl]iron tetrafluoroborate

Iron dicarbonyl

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