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Diborane bond angles

Structural changes as a function of the torsional angle about the B-B bond angle have been studied for the diborane tetrahalides X2B-BX2... [Pg.205]

Although the bond angles are known to vary considerably depending on the metal and halogen, the arrangement is approximately tetrahedral around each metal atom. When the trihalides are dissolved in solvents that are Lewis bases, the dimers separate and complexes containing the monomer and the solvent are formed as a result of Lewis acid-base interactions. Such behavior is similar to that of borane and diborane in that the monomer, BH3, is not stable but adducts of it are. This type of behavior is illustrated in the following equations ... [Pg.216]

Table 8.2 Bond lengths (in units of Bohr) and bond angles (in degrees) of diborane at equilibrium geometry. Table 8.2 Bond lengths (in units of Bohr) and bond angles (in degrees) of diborane at equilibrium geometry.
The M-H-M angle in an Mp(p-H)M linkage is always less than 180°. This bent geometry implies a closed three-center two-electron bond like that in diborane, with an M-M distance that is longer than that in a simple two-center two-electron metal-metal... [Pg.123]

See other pages where Diborane bond angles is mentioned: [Pg.47]    [Pg.205]    [Pg.407]    [Pg.346]    [Pg.4]    [Pg.182]    [Pg.202]    [Pg.120]    [Pg.407]    [Pg.202]    [Pg.396]    [Pg.790]    [Pg.317]    [Pg.444]    [Pg.638]    [Pg.9]    [Pg.790]    [Pg.5]    [Pg.207]    [Pg.26]    [Pg.196]    [Pg.231]    [Pg.324]    [Pg.94]    [Pg.136]    [Pg.132]    [Pg.94]    [Pg.72]    [Pg.5871]    [Pg.396]    [Pg.48]    [Pg.868]    [Pg.90]    [Pg.196]    [Pg.231]    [Pg.396]    [Pg.296]    [Pg.5870]    [Pg.26]    [Pg.183]    [Pg.48]    [Pg.447]   
See also in sourсe #XX -- [ Pg.6 , Pg.9 ]



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Diboran

Diborane

Diborane bonds

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