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Diazocarbene decomposition

We start our discussion by exploring mechanisms and controlling factors of the [(PDI)Ca(THF)3]-catalyzed C-H bond alkylation of MeCHjPh by unsubstituted N2CH2 diazocarbene. First, we discuss the diazocarbene decomposition by [(PDIlCalTHFlg], 4. The calculated energetics, spin population, and geometric... [Pg.27]

Figure 2.1 Potential energy surface of the [(PDI)Ca(THF)3]-catalyzed unsubstituted NjCHj diazocarbene decomposition and metallocarbene formation reaction, as well... Figure 2.1 Potential energy surface of the [(PDI)Ca(THF)3]-catalyzed unsubstituted NjCHj diazocarbene decomposition and metallocarbene formation reaction, as well...
Thus, consistent with the aforementioned analyses, the substitution of H by Ph in carbene carbon makes diazocarbene decomposition thermodynamically more feasible and irreversible. [Pg.34]

See other pages where Diazocarbene decomposition is mentioned: [Pg.19]    [Pg.22]    [Pg.36]    [Pg.37]    [Pg.19]    [Pg.22]    [Pg.36]    [Pg.37]    [Pg.735]    [Pg.735]    [Pg.23]    [Pg.32]   
See also in sourсe #XX -- [ Pg.22 , Pg.23 , Pg.27 , Pg.33 ]



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Diazocarbene

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