Diazirine microwave spectra

Diazirine, fluoromethoxy-nitrogen extrusion, 7, 224 Diazirine, methylvinyl-rearrangement, 7, 221 Diazirines addition reactions to Grignard compounds, 7, 2 0 as carbene precursors, 7, 236 IR spectra, 7, 203 microwave spectrum, 7, 199 molecular spectra, 7, 202-204 nitrogen extrusion, 7, 223 NMR, 7, 202 photoconversion to diazoalkanes, 7, 234 photoisomerization, 7, 221 photolysis, 7, 225-227 quantum chemical investigations, 7, 197 reactions... 

The microwave spectrum of diazirine is consistent with it having a cyclic structure and yields the following molecular dimensions ... 

Pierce and Dobyns (1962) verified structure 5.59 for diazirine on the basis of the rotational microwave spectrum in the frequency region 7.8-41 GHz. The NN, CN,... 

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