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Diatomic molecules dynamical resonances

I shall first discuss briefly the experimental techniques Involved. I shall then review the effects of bond dissociation anharmonlclty in a diatomic molecule. Next I shall introduce the idea of local modes with a simple classical model, and then extend this to a mathematically defined quantum mechanical model which I shall discuss in detail for the case of two symmetry related stretching vibrations, as in the water molecule. I shall then introduce the effects of Fermi resonance, and describe some of our recent work on the dlchloromethane molecule. I shall also describe similar fits to the overtones of carbonyl stretching vibrations in metal carbonyls. Finally I shall comment briefly on the implications of this work for intramolecular vibrational relaxation (IVR) and chemical dynamics. [Pg.461]


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See also in sourсe #XX -- [ Pg.193 , Pg.194 , Pg.195 , Pg.196 , Pg.197 ]




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