Diamagnetic Zeeman effect

Fig. 9.3 Diamagnetic Zeeman effect in Ba (a) zero-field, (b) o polarization with resonances extending into the ionization continuum of (a) (from ref. 2).

Garton, W.R.S. and Tomkins, F.S. (1969). Diamagnetic Zeeman effect and magnetic configuration mixing in long spectral series of Ba I, Astrophys. J. 158,839-845. 

Flygare, W.H. and Benson, R.C. (1971). The molecular Zeeman effect in diamagnetic molecules and the determination of molecular magnetic moments (g values), magnetic susceptabilities, and molecular quadrupole moments, Mol. Phys., 20, 225-250. 

The diamagnetic susceptibility anisotropies and molecular second moments of the electronic charge distributions for COCIF have been calculated by Maksic and Mikac [1303a], and these authors suggested that their calculated values showed that the experimentally derived second moments (calculated from the Zeeman effect in the Stark-modulated microwave... 

Two magnetic susceptibility anisotropies were directly measured by the molecular rotational Zeeman effect as 2xaa-Xbb Xcc=-19-9 0.6 and 2xbb Xaa-Xcc=+12.8 1.2 [1]. Also see the microwave spectral tables [11]. The effect of intramolecular charge transfer on the diamagnetic components Xm was studied [2]. x= -13.19 and the components Xxx= -16.74, Xyy= -11.53, and Xzz= 11-30 (x OH, molecule in xz-plane) were calculated by a finite perturbation method (see below) with a gauge invariant Gaussian basis set. x 16 follows from the Pascal additivity rule [3]. 

Rotational g-values, magnetic susceptibilities and anisotropies, paramagnetic and diamagnetic contribntions, molecular quadrupole moments, electronic charge distributions, spin-rotation and spin-spin coupling parameters, nuclear g-values from the rotational Zeeman effect and nuclear magnetic shieldii parameters from the rotational Zeeman effect as well as indirectly via the paramagnetic contribution to the... 

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