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Di-tert-butylmethane

Apart from fragmentations, the main byproducts isolated are partially fluorinated compounds in which the remaining hydrogen atoms are attached to the most hindered carbon as demonstrated in the case of di-tert-butylmethane (l)11 and in the preparation of dimethyl bexa-fluorobicyelo[1.1.1]pentane-l,3-dicarboxylate(2, R = F). Apart from the perfluorinated products considerable amounts of polyfluoro derivatives are also obtained.12... [Pg.167]

Biirgi H-B, Houshell WD, Nachbar RB Jr, Mislow K (1983) Conformational dynamics of propane, di-tert-butylmethane, and bis(9-triptycyl)methane. An analysis of the symmetry of two threefold rotors on a rigid frame in terms of nonrigid molecular structure and energy hypersurfaces. J Am Chem Soc 105 1427-1438... [Pg.116]

See other pages where Di-tert-butylmethane is mentioned: [Pg.127]    [Pg.108]    [Pg.116]    [Pg.702]    [Pg.127]    [Pg.108]    [Pg.116]    [Pg.702]    [Pg.109]    [Pg.108]   
See also in sourсe #XX -- [ Pg.127 ]



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