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Lewis acids designer

Designer Lewis Acid Catalysts Modern Organic Synthesis... [Pg.3]

Scheme 18.9 Selective reduction assisted by designer Lewis-acid catalysts . ... Scheme 18.9 Selective reduction assisted by designer Lewis-acid catalysts . ...
Yamamoto H, Yanagisawa A, Ishihara K, Saito S (1998) Designer Lewis acids for selective organic synthesis. Pure Appl Chem 70 1507... [Pg.333]

Lewis add can be utilized as a more effective tool for chemical reactions by sophisticated engineering ( designer acid catalysis ) [1]. The goal of such designer Lewis acid is to achieve high reactivity, selectivity, and versatility, upon which the full potential of add catalysts has not yet been realized. [Pg.1]

Modes for Coordination of Lewis Acids to Carbonyl Croups and Designed Lewis Acids... [Pg.250]

First of all, given the well recognised promoting effects of Lewis-acids and of aqueous solvents on Diels-Alder reactions, we wanted to know if these two effects could be combined. If this would be possible, dramatic improvements of rate and endo-exo selectivity were envisaged Studies on the Diels-Alder reaction of a dienophile, specifically designed for this purpose are described in Chapter 2. It is demonstrated that Lewis-acid catalysis in an aqueous medium is indeed feasible and, as anticipated, can result in impressive enhancements of both rate and endo-exo selectivity. However, the influences of the Lewis-acid catalyst and the aqueous medium are not fully additive. It seems as if water diminishes the catalytic potential of Lewis acids just as coordination of a Lewis acid diminishes the beneficial effects of water. Still, overall, the rate of the catalysed reaction... [Pg.161]

The HCFC-225 isomers designed to replace CFC-113 are manufactured by Lewis acid promoted addition of HCFC-21 to tetrafluoroethylene... [Pg.288]

The ammonolysis of phenol (61—65) is a commercial process in Japan. Aristech Chemical Corporation (formerly USS Chemical Division of USX Corporation) currently operates a plant at Ha verb ill, Ohio to convert phenol to aniline. The plant s design is based on Halcon s process (66). In this process, phenol is vapori2ed, mixed with fresh and recycled ammonia, and fed to a reactor that contains a proprietary Lewis acid catalyst. The gas leaving the reactor is fed to a distillation column to recover ammonia overhead for recycle. Aniline, water, phenol, and a small quantity of by-product dipbenylamines are recovered from the bottom of the column and sent to the drying column, where water is removed. [Pg.231]

Many chiral metal complexes with Lewis acid properties have been developed and applied to the asymmetric Diels-Alder reaction. High enantioselectivity is, of course, one of the goals in the development of these catalysts. Enantioselectivity is not, however, the only factor important in their design. Other important considerations are ... [Pg.48]

Figure 6 shows the scans of virgin and modified PS synthesized by using various Lewis acids. The position of each transition is designated by arrows. These transitions, which are observed to occur above room tempera-... [Pg.271]

Step-growth polymerization processes must be carefully designed in order to avoid reaction conditions that promote deleterious side reactions that may result in the loss of monomer functionality or the volatilization of monomers. For example, initial transesterification between DMT and EG is conducted in the presence of Lewis acid catalysts at temperatures (200°C) that do not result in the premature volatilization of EG (neat EG boiling point 197°C). In addition, polyurethane formation requires the absence of protic impurities such as water to avoid the premature formation of carbamic acids followed by decarboxylation and formation of the reactive amine.50 Thus, reaction conditions must be carefully chosen to avoid undesirable consumption of the functional groups, and 1 1 stoichiometry must be maintained throughout the polymerization process. [Pg.13]

Yamamoto H., Yanagisawa A., Ishihara K., Salto S. Designer Lewis Adds for Selective Organic Synthesis Pure Appl. Chem. 1998 70 1507-1512 Keywords Lewis-acid reagents... [Pg.307]

The previous sections have shown that desihcation of ZSM-5 zeohtes results in combined micro- and mesoporous materials with a high degree of tunable porosity and fuUy preserved Bronsted acidic properties. In contrast, dealumination hardly induces any mesoporosityin ZSM-5 zeolites, due to the relatively low concentration of framework aluminum that can be extracted, but obviously impacts on the acidic properties. Combination of both treatments enables an independent tailoring of the porous and acidic properties providing a refined flexibility in zeolite catalyst design. Indeed, desihcation followed by a steam treatment to induce dealumination creates mesoporous zeolites with extra-framework aluminum species providing Lewis acidic functions [56]. [Pg.43]

The designation of hard acids is not restricted to metal cations. For example, in BF3 the small boron atom in its +3 oxidation state is bonded to three highly electronegative fluorine atoms. All the B—F bonds are polarized away from a boron center that is already electron-deficient. Boron trifiuoride is a hard Lewis acid. [Pg.1507]


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