Depolarization spectrum, interaction-induced

Moszynski et al. calculated the interaction-induced polarizability of the helium dimer for the internuclear separations 3computational approach relied on spin-adapted perturbation theory (SAPT) calculations with a large basis set of [5s4p3d2f] size. Subsequently, they determined the polarized and depolarized Raman spectrum of the dimer. The computed polarized spectrum displays fair agreement with experiment. Most important, the computed intensities of the depolarized spectrum agree quite well with the experimental data reported by Proffitt et al7 ... 

---