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Deoxygenations unhindered alcohols

Deoxygenations. Unhindered alcohols are deoxygenated in one step by treatment with PhjP-DEAD and o-nitrobenzenesulfonylhydrazine. ... [Pg.413]

Hong, F.-T., Paquette, L. A. BusSnH-catalyzed Barton-McCombie deoxygenation of alcohols. Single-step process for the reductive deoxygenation of unhindered alcohols. Chemtracts 1998,11, ST-72. [Pg.546]

Unhindered ketones can be deoxygenated by hydrogenation with this catalyst.4 Stcric hindrance can prevent this reaction. Thus, 2-norbomanone does not react, although camphor is reduced. The alcohols corresponding to inactive ketones are reduced. Cyclopentanone is reduced to cyclopentane in 24% yield cyclohexanone is reduced in 90%yield. When successful, this method is a useful one-step deoxygenation. [Pg.520]

See other pages where Deoxygenations unhindered alcohols is mentioned: [Pg.185]    [Pg.360]    [Pg.360]    [Pg.23]    [Pg.24]    [Pg.416]    [Pg.496]    [Pg.1]    [Pg.8]    [Pg.16]   


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Deoxygenation, alcohol

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