1-Deoxy-mannitol, acetyl derivatives

Tri-0-acetyl-l,5-anhydro-2-deoxy-D-arabino-hex-l-enitol (tri-O-acetyl-D-glucal) was the starting point for the synthesis of 1,5-anhy-dro-2-chloro-2-deoxy-D-glucitol or -D-mannitol by way of the 1,2-dichloride (22), which was reduced32 by means of lithium aluminum hydride to the 2-chloro-2-deoxy derivative (23). That the chlorine... 

The well known, D-mannitol-derived bis-aziridine 37 has been used to prepare 6-amino-6-deoxy-2,5-imino-D-glucitol and -1,5-imino-D-mannitol derivatives 38 and 39 as potential glycosidase inhibitors. Treatment of 37 with acetic add, or alternatively allyl alcohol in the presence of an ytterbium catalyst, afforded mono-O-acetylated or -allylated glucitol/mannitol mixtures in 2 1 and 1 2 ratios respectively. ... 

Alditols, Cyclitols and Derivatives Thereof. - 2,5 3,4-Dianhydro-D-altritol, 2,5-aohydro-3,4-0-(l,2-ethanediyl)-D mannitol, pentaerythritol tetraacetate, ribitol tetraacetate, xylitol tetraacetate, D-arabinitol tetraacetate, D, L-arabinitol tetraacetate, 2,4 3,5-di-0-isopropylidene-D-mannitol, 2 hexa-O-acetyl-D-mannitol, allitol hexaacetate, D-mannitol hexaacetate, D, L-mannitol hexaacetate, D-iditol hexaacetate, D, L-iditol hexaacetate, D, L-glucitol hexaacetate, D, L-altritol hexaacetate, L-galacto-D-galacto-decitol (which is C2-symmetric), 5 6-0-benzyl-2,3-0-[(S)-caniphanylidene]-l,4,5-tris-0-pivaloyl-D-myo-inositol, 6D-3,6-di-0-benzyl-l-0-[(S)-camphanyl]-2-deoxy-2,2-difluoro-4,5-0-isopropylidene- y< -inositol, cyclopentane 28. ... 

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