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Daunomycinone 11-deoxy, synthesis

Similar results are obtained with the /htetralone derivatives 12, which are useful building blocks in the synthesis of anthracycline antibiotics. Furthermore, the usefulness of the diastereoselec-tive addition to ot-oxo acetals was impressively demonstrated in the synthesis of (-)-7-deoxy-daunomycinone, which uses the completely stereoselective addition of (trimethylsi-lylethynyl)magnesium chloride to the /i-tetraione acetal 12 (R =OMOM R2 = Br) as the key reaction31. [Pg.108]

See other pages where Daunomycinone 11-deoxy, synthesis is mentioned: [Pg.324]    [Pg.593]    [Pg.593]    [Pg.593]    [Pg.593]    [Pg.470]    [Pg.482]    [Pg.136]    [Pg.136]   
See also in sourсe #XX -- [ Pg.14 , Pg.493 , Pg.494 ]

See also in sourсe #XX -- [ Pg.14 , Pg.493 , Pg.494 ]



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