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Dehydrogenative coupling, metal-catalyse

Experimental data have provided evidence for the involvment of quantum mechanical tunnelling in the coupled cobalt-carbon bond homolysis-substrate radical generation reaction catalysed by methylmalonyl-CoA mutase. ortho-Metallated dirhodium(II) complexes have been used as catalysts in the dia-stereoselective cyclopropanation of menthyl-a-diazo-P-keto ester and C-H insertion of ot-diazo ester. The iridium complexes [Ir(Me)2(L)(r -C5Me5)] (L = PMes, PPhs) have been found to catalyse the dehydrogenative coupling of dimethylphenylsilane in the presence of one-electron oxidants to yield Me2PhSiSiPhMe2. ... [Pg.297]

See other pages where Dehydrogenative coupling, metal-catalyse is mentioned: [Pg.1872]    [Pg.1556]    [Pg.1561]    [Pg.1556]    [Pg.1561]    [Pg.218]    [Pg.254]    [Pg.374]    [Pg.336]    [Pg.1872]    [Pg.92]    [Pg.264]    [Pg.196]    [Pg.423]    [Pg.106]    [Pg.133]    [Pg.253]    [Pg.8]    [Pg.169]    [Pg.99]   
See also in sourсe #XX -- [ Pg.679 ]



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