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Decalinone, enolate

Identify the thermodynamie enolate for each system shown above (2-pentanone enolate A and B 2-methylcyclopentanone enolate A and B decalinone enolate A and B). Also, compare eleetrostatic potential maps for eaeh pair of enolates. What struetural and/or electronic features, if any, appear to dictate which enolate is favored ... [Pg.164]

The formation of the decalinone 174 in 68% yield in the reaction of the dienone 172 with tin(IV) chloride (equation 83) is thought to proceed by way of the enol 17392. The triene 175 (R = H) cyclizes quantitatively to a mixture of the isomeric dodecahy-drophenanthrenes 176 and 177 when treated with tin(IV) chloride at 0 °C (equation 84)93 the homologue 175 (R = Me) reacts analogously94. [Pg.531]

See other pages where Decalinone, enolate is mentioned: [Pg.531]    [Pg.158]   
See also in sourсe #XX -- [ Pg.5 , Pg.11 ]

See also in sourсe #XX -- [ Pg.5 , Pg.11 ]



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