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D-Mannite

When a commercially available C2-symmetric l,4 3,6-dianhydro-D-mannite 29 is chosen as the backbone, reaction of this diol compound with chlorophos-phoric acid diaryl ester gives a series of phosphorate ligands 30. These were tested using the asymmetric hydrogenation of dimethyl itaconate as a model... [Pg.350]

A few efficient bisphosphite ligands have been used for asymmetric hydrogenation of itaconates or a-dehydroamino acid derivatives. Reetz has developed a series of C2-symmetric bisphosphite ligands such as L14, which are based on the structure of 1,4 3,6-dianhydro-D-mannite [78]. The ligands exhibit excellent reactivity and enantioselectivity for the asymmetric hydrogenation of itaconates. [Pg.8]

Die Oxydation von 1,4-Anhydro-D-mannit (9) am Platinkontakt fiihrt zur Bildimg von Mesoweinsaure-mono-glykolsaureather (11), ohne daB eine Zwischenstufe nachgewiesen werden konnte. In analoger Weise entsteht bei der Oxydation von l,4-Anhydro-D,L-talit (12) D,L-Wein-saure-mono-glykolsaureather (14). [Pg.119]

Dianhydro-D-mannit (126), der zwei endo-standige OH-Gruppen enthalt, wird bei 50° C in 6 h nahezu quantitativ zu 1,4 3,6-Dianhydro-D-threo-2,5-hexodiulose (128) oxydiert. Das Monoketon,... [Pg.142]

Bei der katalytischen Oxydation von 2-Acetamido-2-desoxy-3,4 5,6-di-O-isopropyliden-D-mannit entsteht 2-Acetamido-2-desoxy-3,4 5,6-di-0-isopropyliden-D-mannose Das Produkt wurde nicht isoliert, son-dem nach Abspaltung der Isopropylidengruppen chromatographisch nachgewiesen. [Pg.164]

D-glucit 2-Acetamido-2-desoxy-3,4 5,6-di-O-isopropy-liden-D-mannit 100 15 min Aldose 144)... [Pg.193]

MANNITOL HEXANITRATE, wetted with not <40% water, by weight or mixture (NA 0133) (DOT) d-MANNIT-OL HEXANITRATE MANNITRIN MAXITATE MEDEMANOL O NITRANITOL NITRO MANNITE NITROMANNITE (dry) (DOT) NITROMANNITE, wetted with not <40% water, by weight or mixture (NA 0133) (DOT) NITROMANNITOL SDM No. 5... [Pg.862]

Cordycepic acid C PharmMannidex E421 manna sugar D-mannite mannite Mannogem Pearlitol. [Pg.449]

H and C NMR in structure investigations of indole alkaloids 86KPS3. H-NMR data for monoterpenoid indole alkaloids 86H(24)3129. Synthesis of indole alkaloids from maleic anhydride and D-mannite ... [Pg.297]

The synthesis of l,6-di-0-(2-isocyano-3-methylcrotonyl)-D-mannit (antibiotic A 32390 A) required diisocyano compounds as intermediates, which were prepared from the corresponding formamides by dehydration with phosphoryl chloride in yields of 54-74% [1220],... [Pg.418]

Phosphorus Derivatives.- Monobarium 0-D-glucopyranose 6-phosphate, 2-0-[bis(diethylamido)thionophosphate]-3,4-0,0-(diethylam-idothionophosphate)-1,6-anhydro-3-D-glucopyranose,and 2,5-0-(N-diethylamidothionophosphate)-1,3 4,6-di-O-methylene-D-mannit-01.71... [Pg.243]

Maltose Maltose Maltosesinipe Maltose Syrups Mandarinenbaum Mandarin Tree Mandarinenol Mandarin Oil Manilahanf Manila Hemp Maniok Cassava D-Mannit D-Mannitol Meeresalgen Marine Algae Meeresalgenpolysaccharide Seaweed Extracts... [Pg.372]

See other pages where D-Mannite is mentioned: [Pg.342]    [Pg.386]    [Pg.14]    [Pg.980]    [Pg.498]    [Pg.140]    [Pg.142]    [Pg.110]    [Pg.120]    [Pg.120]    [Pg.143]    [Pg.153]    [Pg.163]    [Pg.184]    [Pg.193]    [Pg.193]    [Pg.582]    [Pg.330]    [Pg.272]    [Pg.1075]    [Pg.196]    [Pg.11]    [Pg.1381]    [Pg.1520]    [Pg.133]    [Pg.134]    [Pg.338]    [Pg.184]    [Pg.335]    [Pg.360]   
See also in sourсe #XX -- [ Pg.449 ]



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