Oxidations D-glucose

M. Ohsugi and Y. Inoue, D-Glucose oxidation by Micrococcus sp. grown on acetate, Agric. Biol. Chem., 45 (1981) 1877-1878. 

In vitro assays (by Gliemann and Gammeltoft, 1974) were (c) stimulation of glucose incorporation into lipids and (d) glucose oxidation. 

The reaction of D-glucose oxidation to 5-glucolactone is accelerated by glucose oxidase. The transport of electrons to the electrode was realized with the aid of mediators such studies are historically the first examples of the successful use of the mediator approach in bioelectrocatalysis. 

I. Becerik and F. Kadirgan, Electrocatal) tic properties of platinum particles incorporated with polypyrrole films in D-glucose oxidation in phosphate media, J. Electroanal. Chem., 436, 189-193 (1997). 

Onal, Y, Schimpf, S. and Claus, P. (2004). Structure Sensitivity and Kinetics of D-Glucose Oxidation to D-Gluconic Acid over Carbon-Supported Gold Catalysts, J. Catal, 223, pp. 122-133. 

D-glucose Ru catalysts are mostly efficient. Earlier we demonstrated that Ru-containing catalysts based on HPS are the active catalysts in D-glucose oxidation [24],... 

As might be expected, Ru NPs formed in HPS showed highest catalytic activity in D-glucose oxidation (Table 2, 8-10) while those formed in block copolymers demonstrate mediocre performance. In the HPS-Ru series, the best catalyst (highest activity and selectivity) also contains about 0.9 wt.% of active metal similar to the HPS-Pt series. 

Table 2. Testing of the catalysts in L-sorbose and D-glucose oxidation.

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