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Cysteine-sulfuric acid reaction and, III

The oxidation of glutamic acid to cyanopropionic acid with CAB in acid solution showed an inverse fractional dependence on acidity. Similarly in alkaline medium, the order in alkali is fractional inverse.143 Kinetics of ruthenium(III)-catalysed oxidation of diols with CAB have been obtained. The products arise due to a fission of the glycol bond.144 The oxidation of isatins with CAB, in alkaline solutions, showed a first-order dependence on CAB and isatin and fractional order in alkali. The rates correlate with the Hammett relationship, the reaction constant p being —0.31. The observed results have been explained by a plausible mechanism and the related rate law has been deduced.145 The oxidation of cysteine with CAB in sulfuric acid medium is first order in CAB and cysteine and the rate is decreased with an increase in the hydrogen ion concentration.146... [Pg.108]

See other pages where Cysteine-sulfuric acid reaction and, III is mentioned: [Pg.212]    [Pg.365]    [Pg.212]    [Pg.448]    [Pg.6357]    [Pg.187]    [Pg.82]    [Pg.94]    [Pg.49]    [Pg.46]    [Pg.175]    [Pg.248]    [Pg.330]    [Pg.5459]    [Pg.49]   
See also in sourсe #XX -- [ Pg.83 , Pg.90 ]



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