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Cyclopropane reactivity towards bromine

Although cyclopropane and cyclobutane have similar strain energies, they differ markedly in their reactivity toward electrophiles. Thus, whereas cyclopropane reacts readily with bromine to give 1,3-dibromopropane, cyclobutane does not react with bromine. [Pg.733]

This cyclopropane acid is i. uch lees reactive towards addition reagents than any of the ring compounds thus far dealt with. It is not attacked bji cold saturated aqueous liydrcfcroi.ic acia (although it dissolves in it) and is lijcewise uhreactive towards bromine in... [Pg.971]

Similarly, cyclopropane reacts readily with electrophiles such as bromine, whereas cyclobutane and the larger carbocycles are inert. This carries over to the corresponding bicyclic compounds. Bicyclobutane is extraordinarily reactive towards electrophiles, bicyclo[2.1.0]pentane has high reactivity, but bicyclo[2.2.0]hexane is almost inert". This does not correspond to differences in driving force for the reactions, in fact a reverse correlation is found ... [Pg.2]

See other pages where Cyclopropane reactivity towards bromine is mentioned: [Pg.967]    [Pg.15]    [Pg.966]    [Pg.966]    [Pg.451]    [Pg.452]    [Pg.40]    [Pg.46]   
See also in sourсe #XX -- [ Pg.163 ]

See also in sourсe #XX -- [ Pg.157 ]

See also in sourсe #XX -- [ Pg.163 ]



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