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Cyclopentanols 3-alkoxy

Hypohalites (RO—Hal) are similar to nitrates (see p. 155) in their photochemical behaviour. Ultraviolet irradiation gives an (n,Jt ) excited state that cleaves to form an alkoxy radical and a halogen atom. The radical may undergo alpha-cleavage before recombination with the halogen atom occurs, and this accounts for the formation of 5-iodopentanal (5.69) from the hypoiodite of cyclopentanol such hypoiodites are generated in situ from the alcohol, iodine and mercury(ll) oxide. In open-chain systems the alkoxy radical can... [Pg.87]

See other pages where Cyclopentanols 3-alkoxy is mentioned: [Pg.225]    [Pg.300]    [Pg.2175]    [Pg.547]    [Pg.2175]    [Pg.2408]    [Pg.12]    [Pg.31]    [Pg.225]    [Pg.1176]   
See also in sourсe #XX -- [ Pg.43 ]



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