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Cyclopentadecanone monooxygenase

Synthesis of Optically Pure Chiral Lactones by Cyclopentadecanone Monooxygenase-catalyzed Baeyer-Villiger Oxidations... [Pg.344]

Scheme 3.90 Extensive substrate profiling of cyclopentadecanone monooxygenase as Baeyer-Villiger biocatalyst reveals novel regiodivergent oxidations [65d]. Scheme 3.90 Extensive substrate profiling of cyclopentadecanone monooxygenase as Baeyer-Villiger biocatalyst reveals novel regiodivergent oxidations [65d].
In fact, Mihovilovic and coworkers have demonstrated for a series of terpinones that this is indeed the case [65dj. For instance, on treatment with cyclopentadecanone monooxygenase (CPDMO) the enantiomers of trans-dihydrocarvone [(+)-470 and (—)-472] are oxidized to the enantio- and regioisomerically pure lactones 471 and 473, respectively, with quantitative conversion. [Pg.208]

M.J. Fink, T.C. Fischer, F. Rudroff, H. Dudek, M.W. Fraaije, M.D. Mihovilovic, Extensive substrate profiling of cyclopentadecanone monooxygenase as Baeyer-Villiger biocatalyst reveals... [Pg.281]

See other pages where Cyclopentadecanone monooxygenase is mentioned: [Pg.244]    [Pg.244]    [Pg.111]    [Pg.112]    [Pg.348]    [Pg.344]    [Pg.350]    [Pg.419]    [Pg.344]    [Pg.244]    [Pg.244]    [Pg.111]    [Pg.112]    [Pg.348]    [Pg.344]    [Pg.350]    [Pg.419]    [Pg.344]    [Pg.110]    [Pg.114]    [Pg.360]   


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Cyclopentadecanone monooxygenase CPDMO)

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