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2-cyclohexenone alkanone

The nucleophilic intermediate obtained by treatment of enones with MejCuLi in diethyl ether at 273 K under nitrogen has been rnade to give aldol condensation products with zinc chloride and excess acetaldehyde. Thus cyclohexenone gave 97 % of (34), which on dehydration gave the enone (35) in 87 % yield. Introduction of an isoprene function onto an alicyclic system has been accomplished " via the reagent (36) with saturated and unsaturated alkanones at low temperatures (195 K). [Pg.209]


See other pages where 2-cyclohexenone alkanone is mentioned: [Pg.2008]    [Pg.2341]    [Pg.2488]    [Pg.2488]    [Pg.2008]    [Pg.2341]    [Pg.2488]    [Pg.2488]    [Pg.2341]    [Pg.2342]    [Pg.2342]    [Pg.2342]    [Pg.2342]    [Pg.1193]    [Pg.2488]    [Pg.436]    [Pg.436]   
See also in sourсe #XX -- [ Pg.1338 , Pg.1356 , Pg.1358 , Pg.1361 ]




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2-Cyclohexenone

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