Cyclohexene, photooxidation products

The values obtained for the rate coefficients of these reactions were (1.6 0.6) x 106 and (3 1) x 106 l.mole 1.sec 1 respectively. Similar values of the rate coefficients for the recombination of peroxy radicals were obtained from studies of the photooxidation of cyclohexene and other olefins by the rotating sector technique75. Production of peroxy radicals was presumably via the reactions... 

Photooxidation of cycloalkenes. The Fe( I,-catalyzed photooxidation of cycloal-kenes in pyridine can lead to three types of products, depending on the substitution pattern of the cycloalkenes. The three general reactions are shown in equations (l)-(lll) for the oxidation of cyclohexenes. 

The issues of sensitizer degradation and purification of the oxidation products were taken into account by DiMagno et al., who used the electron-deficient fluorous porphyrin 15 (5,10,15,20-tetrakis(heptafluoropropyl)porphyrin) as a sensitizer in the photooxidation of cyclohexene and allylic alcohols in CHjCN/perfluorohexanes [26]. 

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